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In some molecules and under some conditions, isomerisation occurs spontaneously. When the isomerisation occurs intramolecularly it is considered a rearrangement reaction. — “Isomerisation - Wikipedia, the free encyclopedia”, en.wikipedia.org
This article does not cite any references or sources. Please help improve this article by adding citations to reliable sources. It is rapidly and reversibly isomerised to glyceraldehyde 3-phosphate. — “Dihydroxyacetone phosphate - Wikipedia, the free encyclopedia”, en.wikipedia.org
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) In most vertebrates, propionyl-CoA is carboxylated to D-methylmalonyl-CoA, which is isomerised to L-methylmalonyl-CoA. — “Calcium propanoate - Wikipedia, the free encyclopedia”, en.wikipedia.org